Napoli lost 2-0 at Benfica Wednesday night while Juventus beat Pafos 2-0 in Turin.
Four.time Serie A winner and leaders Napoli went down to goals from Richard Rios and Leandro Barreiro while 36-time scudetto winner and seventh-placed Juve's goals against the Cypriots came from Weston McKennie and Jonathan David.
Both Italian teams are in the play-off section of the UCL standings with the last two of eight qualifying matches to come in February.
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